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Can we sweep our CO2 emissions under the rug?

“Public opinion is a major obstacle to underground CO2 storage”

with Laurent Catoire, Head of Chemistry and Processes Unit at ENSTA Paris (IP Paris)
On March 8th, 2022 |
3 min reading time
Laurent Catoire
Laurent Catoire
Head of Chemistry and Processes Unit at ENSTA Paris (IP Paris)
Key takeaways
  • Every year, approximately 270 million tons of CO2 are emitted into the atmosphere: ~0,1% of which are currently captured.
  • The storage of CO2 emissions underground is done through various physical or chemical capture mechanisms in specific geological environments.
  • Existing operations show that there is no major technological obstacle for the geological storage of CO2.
  • The main issue would be acceptability. The possibility – however small – of CO2 leakage in the short or long-term poses a potential hazard to local populations.
  • Thus, for now, projects are focused on the storage of CO2 at sea, like the Norwegian Sea.

The cap­ture and sto­rage of car­bon dioxide is a tech­no­lo­gy that could make it pos­sible to conti­nue using fos­sil fuels during much of the 21st cen­tu­ry. It par­ti­cu­lar­ly concerns coal, a cen­tral resource for many coun­tries since there are still more than 2,500 ther­mal power plants in the world. This ener­gy is used for the pro­duc­tion of elec­tri­ci­ty and heat (coge­ne­ra­tion) for indus­trial and domes­tic pur­poses. Coal-fired and gas-fired ther­mal power plants are rela­ti­ve­ly abun­dant, affor­dable, avai­lable and loca­ted all over the world. As such, they streng­then the secu­ri­ty and sta­bi­li­ty of ener­gy systems.

Eco­no­my and demo­gra­phics being what they are, the ener­gy tran­si­tion will take time – seve­ral decades at least. While we wait for the green hydro­gen eco­no­my, we must none­the­less conti­nue to live, all the while bat­tling against the green­house effect cau­sed by CO2 emis­sions. As such, car­bon cap­ture and sto­rage offers a solu­tion to help buy us some valuable time. CO2 emis­sions represent approxi­ma­te­ly 270 mil­lion tons eve­ry year but today only 0.1% of indus­trial emis­sions are cap­tu­red. Need­less to say, there is work to be done !

Storing CO2 underground

Nor­mal­ly, under­ground sto­rage of CO2 is achie­ved through various methods of phy­si­cal or che­mi­cal cap­ture, and it requires strict geo­lo­gi­cal condi­tions. As such, only very pre­cise geo­lo­gi­cal envi­ron­ments can be used. In par­ti­cu­lar, the geo­lo­gi­cal for­ma­tions must not only be capable of contai­ning the CO2 but must also prevent late­ral and/or ver­ti­cal migra­tion of the gas. Any leaks could conta­mi­nate potable ground­wa­ter at low depths, infil­trate the ground, or more impor­tant­ly reach the atmosphere.

The geo­lo­gi­cal for­ma­tions used for CO2 sto­rage are main­ly oil and gas reser­voirs, as well as deep saline aqui­fers found in sedi­men­ta­ry basins. The sto­rage of gas (inclu­ding CO2) in these envi­ron­ments has been pro­ven to work on a large scale. It can even be per­for­med during oil extrac­tion ope­ra­tions (secon­da­ry reco­ve­ry), natu­ral gas sto­rage, and aci­dic gas removal.

Some of the risks asso­cia­ted with CO2 cap­ture and sto­rage are simi­lar and com­pa­rable to those of any other indus­trial acti­vi­ty for which safe­ty and regu­la­to­ry pro­to­cols are alrea­dy esta­bli­shed. At the moment, there are only few ope­ra­tions in the world where CO2 is injec­ted and sto­red in the ground (USA, Aus­tra­lia, Cana­da, Chi­na and UK). Most of the time, if not exclu­si­ve­ly, it is done in the context of an ope­ra­tion moti­va­ted by dri­vers other than cli­mate change, such as oil pro­duc­tion or regu­la­to­ry requi­re­ments for the use of hydro­gen sul­fide (H2S).

A complicated start

Exis­ting ope­ra­tions show that there is no major tech­no­lo­gi­cal obs­tacle for the geo­lo­gi­cal sto­rage of CO2. Chal­lenges and blocks thus lie elsew­here. They main­ly stem from the high cost of the ope­ra­tion, par­ti­cu­lar­ly for dilu­ted flows, like those from power plants and indus­trial com­bus­tion processes.

Spe­ci­fic risks asso­cia­ted with CO2 sto­rage relate to the ope­ra­tio­nal phase (the injec­tion, to put it sim­ply) and the post-ope­ra­tio­nal phase. The grea­test concern is lin­ked with the pos­sible risk of CO2 lea­kage in the short or long term. Nega­tive effects include the glo­bal cli­mate impact of the return of CO2 in the atmos­phere, as well as the local health and envi­ron­men­tal risks, which must the­re­fore be cor­rect­ly asses­sed and managed.

The other obs­tacle is the­re­by more media-dri­ven. We are concer­ned that public opi­nion might reject this tech­no­lo­gy and that it could affect the large-scale imple­men­ta­tion of CO2 geo­lo­gi­cal sto­rage. Indeed, who will accept such a sto­rage site in their town ? The risks asso­cia­ted with the trans­por­ta­tion and injec­tion of car­bon dioxide are rea­so­na­bly well unders­tood. Howe­ver, there exists a small pos­si­bi­li­ty that the CO2 sto­red under­ground could leak from a reser­voir, either by an uni­den­ti­fied migra­tion path­way, or because of a well defect.

The threat that it could represent must be asses­sed in com­pa­ri­son with vol­ca­nic CO2 emis­sions, which are natu­ral. Dif­fuse CO2 emis­sions from the soil or via car­bo­na­ted sources in vol­ca­nic areas do not seem to represent a threat, pro­vi­ded that the CO2 can dis­perse in the atmos­phere. Howe­ver, CO2 is dan­ge­rous when it accu­mu­lates in clo­sed spaces. Thus, large clouds of CO2 lin­ked with sud­den emis­sions coming from vol­ca­nic vents or cra­ters are a dead­ly threat. The Lake Nyos disas­ter in 1986 in Came­roon, which resul­ted in 1,800 deaths from CO2 asphyxia­tion, serves as a reminder.

More acceptable solutions

Even if few ana­lo­gies exist bet­ween such an event and a pos­sible CO2 leak from a reser­voir, the risk is not null. This disas­ter is the­re­fore like­ly to come up in the media and will arouse hos­ti­li­ty in popu­la­tions living in proxi­mi­ty of a poten­tial sto­rage site. Murphy’s law will pre­vail over any other consideration.

In this case, only one option remains viable : sto­ring CO2 in the open sea. In Europe, the Nor­we­gian Sea is often cited. Howe­ver, this does not mean that there would not be any impact in the event of a release of CO2. Lea­kage of gas under the sea would result in water aci­di­fi­ca­tion around the sto­rage site, with pos­sible damage for fau­na and flo­ra close by. This has been exa­mi­ned in eco­toxi­co­lo­gy stu­dies. But in any case, this CO2 release – even in the event of a signi­fi­cant leak – would not direct­ly affect human health since it would be under the sea. This is the­re­fore reas­su­ring for the public. Social accep­tance of this alter­na­tive is the­re­fore the only variable capable of acce­le­ra­ting the imple­men­ta­tion of tech­no­lo­gies for redu­cing anthro­po­ge­nic CO2 emis­sions in the atmosphere.

Contributors

Laurent Catoire

Laurent Catoire

Head of Chemistry and Processes Unit at ENSTA Paris (IP Paris)

Laurent Catoire is a professor in applied chemical kinetics, in particular in combustion and in general in all reactive systems. After a DGA thesis, he has been working for 30 years on reactive systems that are little studied, poorly known but with important or potentially important applications (hypergolic systems in space propulsion, civil and military energetic materials (explosives, propellants and gas generators), energetic ionic liquids, nanothermites, aluminium combustion, metal combustion, etc).

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